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INNOVATIVE APPLICATION OF MEMBRANE TECHNOLOGY FOR ULTRAFILTRATRION OF HOTBRINE

In the chlor-alkali industry, the main raw material is salt (Sodium chloride). The industrial grade salt consists of impurities such as salts of calcium, magnesium, silica. The impurities have to be removed before feeding into the electrolysers.

The conventional system of brine purification is done by precipitation followed by dual filtration – first through anthracite bed followed by alpha cellulose pre-coat filter.


The disadvantages of dual filters are as follows:

 Power consumption is high as pressure drop across the two filters are to be taken into account.

 Power consumption progressively increases with increase in pressure drop.

 The pre-coat filtration is semi-automatic as a filtration-aid for additional solid waste generation and also contributes to increase in TOC in brine.

 The quality of brine from pre-coat still has suspended solids generally over 0.5 ppm. This has a long term negative effect on secondary brine resins and electrolyser membrane.

 The conventional system of anthracite and precoat involves extensive cost for installation and maintenance but still generates additional solid wastes.

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PRODUCT DESCRIPTION :

The system consists of Ultrafiltration membranes which are designed for particulate removal in the brine stream. Due to tiny opening 0.05 microns) in the membranes all suspended particles including Calcium, Magnesium Silica , and organics are retained, while permitting the passage of clear brine. The particulates thus separated get deposited inside the membrane lumen and are periodically removed out of the system by a change in the direction of the brine flow. (back wash)

Ultrafiltration membranes are also very effective in the removal of colloidal organics and are an excellent pretreatment tool for the treatment of brine in Chlor-alkali Industry.

The Ultrafiltration system can replace the conventional anthracite and precoat filters. The brine from the Ultrafiltration system is ultrapure with respect to the suspended solids.

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ULTRAFILTRATION :

Brine from the clarifier is to be taken directly to the ultrafiltration unit without any media filter.

The system operates in the following sequence:


UF Feed          UF Product


Filtration Backwash

During backwash the accumulated particulates are collected and flushed out of the system.

The brine from the backwash steps are collected and taken back to the clarifier. They contain only suspended solids. Hence, practically there is no wastage of brine.

Chemical cleaning is required when the differential pressure across the membrane system increases beyond 0.7 kgs/cm2 (10.5 psig) Acidified depleted brine is used for chemical cleaning.

The chemical wash is collected in a separate tank , neutralised for acidity and free chlorine and fed to the saturator.

The operation can be controlled by a Programmable Logic Controller, from the Central Control room.

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PERFORMANCE OF U.F. vs. CONVENTIONAL FILTERS


BENEFITS :


 ECO-FRIENDLY AS THERE IS NO EFFLUENT GENERATION.

 SUBSTANTIALLY REDUCES FOOT-PRINT AREA.

 REDUCES SOLID WASTES.


 REDUCES TOC IN THE FEED BRINE TO SECONDARY RESIN TOWER DUE TO ELIMINATION OF FILTER AIDS.

 INCREASE IN THE EFFICIENCY OF THE ION EXCHANGE COLUMNS DUE TO LOWER SUSPENDED SOLIDS CONTENT.

 DUE TO PHENOMENOL DECREASE IN THE SUSPENDED SOLIDS, THE LIFE OF THE ION EXCHANGE MEMBRANE WILL INCREASE.

 THE UNIT IS PLC OPERATED,MINIMUM MANPOWER REQUIRED.

 CONSISTENT QUALITY OF PRODUCT BRINE IRRESPECTIVE OF FLUCTUATIONS IN FEED BRINE QUALITY FROM THE CLARIFIER.

 REDUCES LARGE PIPING.

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SAVINGS :

 Power savings < 0.2 kwH/cum

  Reduction in man-power

  Elimination of Anthracite filter

  Elimination of Alpha Cellulose System.

  Reduction in (make up) Ion Exchange resin.

  Savings in Consumption of chemicals - HCl, NaOH

  Reduction in maintenance of Alpha cellulose and Anthracite filter.

Total saving - direct and indirect : Cost approx. Rs. 3.5 Million (US$ 7440)/ year for typical 100 T/day plant

The above savings are without taking into consideration the indirect benefits like reduction in TOC and secondary brine pressure drop and thereby resulting in power saving and enhancement in the life of resin and membrane.

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Dupont - Nafion Products, USA has taken up the global marketing of UF system for brine filtration.

An agreement was entered, recently with Dupont USA, in Singapore.

























































































UF MEMBRANE MODULES - DESPATCHED recently TO U.S.A.





 

DEVELOPMENT OF 400 DIA MEMBRANE:
With the urge to develop membrane modules of higher area, MTL successfully developed, departing from the standard / conventional sizes, membrane module of 400 dia with membrane surface area of 120 sqm unlike standard area of 35 sqm. This innovative 400 dia membrane has been applied for patent.

These membrane modules are working very well, for the past one year, in the treatment of hot brine in our chlor-alkali plant.

MTL has also developed out to in membranes, which is the cutting edge technology, with more membrane surface area, compared to in to out configuration. However, this can be used for specific applications only.




ADVANTAGES OF 400 MM DIA MEMBRANE MODULE
   Proven technology
   Cost effective
   Proprietary design - none can compete
   Compact
   Lesser Foot Print
   Less Power consumption
   Low capital cost than any other system
   Very low maintenance cost
   Cost per unit production very less



































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